NON-ISOTHERMAL KINETICS OF SOLID-PHASE DECOMPOSITION OF MIXTURES OF OCTOGEN WITH NITRO-NITROZOAMINES

V.O. Popov, V.N. Komov, E.M. Popenko, A.V. Sergienko
DOI: 10.25699/SSSB.2021.40.6.022 Download PDF
Abstract: The formal-kinetic characteristics of the thermal decomposition of nitro-nitrosoamines and their mixtures with HMX have been determined. The decomposition reaction of nitroso analogs of HMX and nitro-nitroso derivatives of tetraazadecalin is characterized by a lower activation energy compared to HMX, and proceeds at a higher rate. The analysis of the activation parameters of the thermal decomposition of the mixtures was carried out, the activating effect of the nitroso derivatives of tetraazadecalin on the decomposition of HMX was established.
Index terms: octogen, thermal decomposition, activation energy.

Contacts

Russia, 659305, Altai region, Biysk,
Trofimova Street, 27, room 404B
Tel. + 7-923-162-93-27
(executive secretary -
Golykh Roman Nikolayevich)
e-mail: info@s-sibsb.ru

The certificate