Abstract: The formal-kinetic characteristics of the thermal decomposition of nitro-nitrosoamines and their mixtures with HMX have been
determined. The decomposition reaction of nitroso analogs of HMX and nitro-nitroso derivatives of tetraazadecalin is characterized
by a lower activation energy compared to HMX, and proceeds at a higher rate. The analysis of the activation parameters of the
thermal decomposition of the mixtures was carried out, the activating effect of the nitroso derivatives of tetraazadecalin on the
decomposition of HMX was established.
Index terms: octogen, thermal decomposition, activation energy.